期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 10, 页码 2667-2672出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201305950
关键词
chemical exchange; IR spectroscopy; photochemistry; vibrational lifetimes; VIPER 2D-IR spectroscopy
资金
- Alexander von Humboldt Foundation
- Fonds der Chemischen Industrie
Two-dimensional exchange spectroscopy (2D EXSY) is a powerful method to study the interconversion (chemical exchange) of molecular species in equilibrium. This method has recently been realized in femtosecond 2D-IR spectroscopy, dramatically increasing the time resolution. However, current implementations allow the EXSY signal (and therefore the chemical process of interest) only to be tracked during the lifetime (T-1) of the observed spectroscopic transition. This is a severe limitation, as typical vibrational T-1 are only a few ps. An IR/Vis pulse sequence is presented that overcomes this limit and makes the EXSY signal independent of T-1. The same pulse sequence allows to collect time-resolved IR spectra after electronic excitation of a particular chemical species in a mixture of species with strongly overlapping UV/Vis spectra. Different photoreaction pathways and dynamics of coexisting isomers or of species involved in different intermolecular interactions can thus be revealed, even if the species cannot be isolated because they are in rapid equilibrium.
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