期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 6, 页码 1611-1615出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309755
关键词
amino alcohols; chemoselective catalysis; cooperative effects; proton transfer; synthetic methods
资金
- MEXT
- CREST from JST
- Uehara Memorial Foundation
- Takeda Science Foundation
- Kyushu University Interdisciplinary Programs in Education and Projects in Research Development
- Grants-in-Aid for Scientific Research [24106733, 24890158] Funding Source: KAKEN
A highly chemoselective conjugate addition of alcohols in the presence of amines is described. The cooperative nature of the catalyst enabled chemoselective activation of alcohols over amines, allowing the conjugate addition to soft Lewis basic ,-unsaturated nitriles. Divergent transformation of the nitrile functionality highlights the utility of the present catalysis.
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