期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 45, 页码 12201-12204出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407413
关键词
ene reaction; photochemistry; reaction mechanisms; ruthenium; singlet oxygen
资金
- NSFC [21102097]
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
Secondary enaminones were oxidized by photochemically generated singlet oxygen, followed by nucleophilic addition of alcohol and an unexpected 1,2-acyl migration to afford quaternary amino acid derivatives. An ene-type reaction pathway is proposed. It is distinctively different from the typical [2+2] addition of singlet oxygen to a C=C bond pathway.
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