期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 39, 页码 10377-10380出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201405453
关键词
chromium; high-pressure chemistry; mixed anion phases; oxyhydrides; perovskites
资金
- Hakubi Project
- MEXT [24248016, 25810040]
- JSPS through FIRST Program
- JSPS through CREST
- Grants-in-Aid for Scientific Research [25810040] Funding Source: KAKEN
We report a novel oxyhydride SrCrO2H directly synthesized by a high-pressure high-temperature method. Powder neutron and synchrotron X-ray diffraction revealed that this compound adopts the ideal cubic perovskite structure (Pm (3) over barm) with O2-/H- disorder. Surprisingly, despite the non-bonding nature between Cr 3d t(2g) orbitals and the H 1s orbital, it exhibits G-type spin ordering at T-N approximate to 380 K, which is higher than that of RCrO3 (R=rare earth) and any chromium oxides. The enhanced TN in SrCrO2H with four Cr-O-Cr bonds in comparison with RCr3+O3 with six Cr-O-Cr bonds is reasonably explained by the tolerance factor. The present result offers an effective strategy to tune octahedral tilting in perovskites and to improve physical and chemical properties through mixed anion chemistry.
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