期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 4, 页码 1270-1274出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201409617
关键词
alkenes; fluoroalkylation; halides; palladium; synthetic methods
资金
- National Basic Research Program of China (973 Program) [2012CB821600, 2015CB931900]
- NSFC [21425208, 21421002, 21172242, 21332010]
- SIOC
An efficient palladium-catalyzed Heck-type reaction of fluoroalkyl halides, including perfluoroalkyl bromides, trifluoromethyl iodides, and difluoroalkyl bromides, has been developed. The reaction proceeds under mild reaction conditions with high efficiency and broad substrate scope, and provides a general and straightforward access to fluoroalkylated alkenes which are of interest in life and material sciences.
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