期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 44, 页码 11868-11871出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201407948
关键词
C-H activation; electrochemistry; heterocycles; radical reactions; reaction mechanisms
资金
- NIH/NIGMS [GM-106210]
- Pfizer Inc
- Teijin Pharma Ltd
Electrochemical reactions are shown to be effective for the C-H functionalization of a number of heterocyclic substrates that are recalcitrant to conventional peroxide radical initiation conditions. Monitoring reaction progress under electrochemical conditions provides mechanistic insight into the C-H functionalization of a series of heterocycles of interest in medicinal chemistry.
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