期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 8, 页码 2203-2207出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310544
关键词
azides; C-H amidation; esters; iridium; weakly coordinating groups
资金
- Institute of Basic Science (IBS)
- Ministry of Science, ICT & Future Planning, Republic of Korea [IBS-R010-D1-2014-A00] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
An iridium-catalyzed direct CH amidation of weakly coordinating substrates, in particular of those bearing ester and ketone groups, under very mild conditions has been developed. The observed high reaction efficiency was achieved by the combined use of acetic acid and lithium carbonate as additives.
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