期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 6, 页码 1488-1504出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201303971
关键词
energy storage; conversion; lithium-ion batteries; mixed metal oxides; oxygen reduction; supercapacitors
资金
- National Natural Science Foundation of China [11079004, 90922016]
A promising family of mixed transition-metal oxides (MTMOs) (designated as A(x)B(3-x)O(4); A, B=Co, Ni, Zn, Mn, Fe, etc.) with stoichiometric or even non-stoichiometric compositions, typically in a spinel structure, has recently attracted increasing research interest worldwide. Benefiting from their remarkable electrochemical properties, these MTMOs will play significant roles for low-cost and environmentally friendly energy storage/conversion technologies. In this Review, we summarize recent research advances in the rational design and efficient synthesis of MTMOs with controlled shapes, sizes, compositions, and micro-/nanostructures, along with their applications as electrode materials for lithium-ion batteries and electrochemical capacitors, and efficient electrocatalysts for the oxygen reduction reaction in metal-air batteries and fuel cells. Some future trends and prospects to further develop advanced MTMOs for next-generation electrochemical energy storage/conversion systems are also presented.
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