期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 52, 页码 14494-14498出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201406461
关键词
biomimetic synthesis; cycloaddition; dimerization; natural products; photochemistry
资金
- National Science Foundation of China [21102081, 21272133, 81273397]
- Chinese National Science & Technology Major Project Key New Drug Creation and Manufacturing Program [2013ZX09508104]
- Beijing Natural Science Foundation [2132037]
- Science Foundation of Shanghai [12XD1405700]
- China Postdoctoral Science Foundation [2014M550255]
- Tsinghua-Giti project
Starting from xanthatin, the biomimetic synthesis of 4 beta,5 beta-epoxyxanthatin-1 alpha,4 alpha-endoperoxide, a novel monomeric xanthanolide, has been achieved. Moreover, four unprecedented xanthanolide dimers were synthesized by three different dimerizations of xanthatin, either in a head-to-head or head-to-tail fashion. Notably, these dimeric compounds were firstly identified as artifacts in the laboratory, and two of them, mogolides A and B, proved to be natural products present in the Xanthium mogolium Kitag plant.
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