期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 37, 页码 9926-9930出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201405842
关键词
alkaloids; natural products; organocatalysis; synthetic methods; total synthesis
资金
- EPFL (Switzerland)
- Swiss National Science Foundation (SNSF)
- Swiss National Centres of Competence in Research NCCR-Chemical Biology
- COST action [CM0905]
- Swiss State Secretariat for Education and Research
In the presence of a catalytic amount of an imidodiphosphoric acid, enantioselective desymmetrization of bicyclic bislactones by reaction with alcohols took place smoothly to afford enantiomerically enriched monoacids having an all-carbon stereogenic center. Concise catalytic enantioselective syntheses of both (-)-rhazinilam and (-)-leucomidineB were subsequently developed using (S)-methyl 4-ethyl-4-formylpimelate monoacid as a common starting material.
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