期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 3, 页码 801-804出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201409902
关键词
alkenes; cobalt; double-bond migration; isomerization; stereoselectivity
The cobalt-catalyzed selective isomerization of terminal alkenes to the thermodynamically less-stable (Z)-2-alkenes at ambient temperatures takes place by a new mechanism involving the transfer of a hydrogen atom from a Ph2PH ligand to the starting material and the formation of a phosphenium complex, which recycles the Ph2PH complex through a 1,2-H shift.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据