Spectrophotometric determination of trace amounts of uranium(VI) in water samples after mixed micelle-mediated extraction

A cloud point extraction process using mixed micelle of the cationic surfactant CTAB and non-ionic surfactant TritonX-114 to extract uranium(VI) from aqueous solutions was investigated. The method is based on the color reaction of uranium with pyrocatechol violet in the presence of potassium iodide in hexamethylenetetramine buffer media and mixed micelle-mediated extraction of complex. The optimal extraction and reaction conditions (e.g. surfactant concentration, reagent concentration, effect of time) were studied and the analytical characteristics of the method (e.g. limit of detection, linear range, preconcentration, and improvement factors) were obtained. Linearity was obeyed in the range of 0.20-10.00 ng mL(-1) of uranium(VI) ion and the detection limit of the method is 0.06 ng mL(-1). The interference effect of some anions and cations was also tested. The method was applied to the determination of uranium(VI) in tap water, waste-water and well water samples. (c) 2006 Elsevier B.V. All rights reserved.