期刊
SYNLETT
卷 -, 期 3, 页码 411-414出版社
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2007-967951
关键词
ionic liquid; veratryl alcohol; oxidation; iron(III) porphyrins; horseradish peroxidase (HRP)
3,4-Dimethoxybenzyl alcohol (veratryl alcohol) is a model compound for lignin substructures and its oxidation with H2O2 catalyzed by iron(III) porphyrins and horseradish peroxidase (HRP) in ionic liquids has been described. Veratraldehyde and 2-hydroxymethyl-5-methoxy-2,5-cyclohexadiene-1,4-dione were the two major products of the oxidation of veratryl alcohol at room temperature. The iron(III) porphyrin or HRP immobilized in ionic liquids showed increased catalytic activity and can be recycled and this is believed due to the stabilization of highvalent oxo-iron(IV) pi-cation radical intermediate generated in the reaction.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据