期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 15, 页码 3904-3908出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201310193
关键词
antitumor agents; organoboranes; CH functionalization; nitrogen heterocycles; synthetic methods
资金
- National Science Foundation of China [21202093]
- Young Scientist Foundation Grant of Shandong Province [BS2013YY001]
Described is a practical and universal CH functionalization of readily removable N-benzyl and N-allyl carbamates, with a wide range of nucleophiles at ambient temperature promoted by Ph3CClO4. The metal-free reaction has an excellent functional-group tolerance, and displays a broad scope with respect to both N-carbamates and nucleophile partners (a variety of organoboranes and CH compounds). The synthetic utility in target- as well as diversity-oriented syntheses is demonstrated.
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