期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 827, 期 1-3, 页码 201-205出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2006.05.032
关键词
tribenzo-S2O2 macrocycle; binuclear complex; silver picrate; anion-ligand interaction; NMR; pi-pi stacking
From the reaction of tribenzo-S2O2 macrocyclic ligand (L-1) and silver picrate (AgPic), a unique binuclear complex [Ag-2(L-1)(2)(PiC)(2)] (1) has been obtained. The species I has been characterised by single-crystal X-ray diffraction analysis providing a definitive proof of its cyclic dirner structure as well as the anion-ligand pi-pi stacking interactions between L-1 and Pic(-). The result of a comparative NMR experiment suggests that the solid structure of 1 is also retained in solution. (c) 2006 Elsevier B.V. All rights reserved.
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