期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 54, 期 6, 页码 1812-1816出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201410154
关键词
cathode; graphene; lithium; nanostructures; nitrogen
资金
- 973 Program of China [2012CB933404, 2013CBA01602, 2014CB239701]
- Natural Science Foundation of China [61235007, 21174083, 21320102006, 21102091, 21372155]
- Ph.D. Programs Foundation of Ministry of Education of China for Young Scholars [20110073120039]
- Program for Professor of Special Appointment (Eastern Scholar)
- ERC 2DMATER
It is highly desirable to develop electroactive organic materials and their derivatives as green alternatives of cathodes for sustainable and cost-effective lithium-ion batteries (LIBs) in energy storage fields. Herein, compact two-dimensional coupled graphene and porous polyaryltriazine-derived frameworks with tailormade pore structures are fabricated by using various molecular building blocks under ionothermal conditions. The porous nanosheets display nanoscale thickness, high specific surface area, and strong coupling of electroactive polyaryltriazine-derived frameworks with graphene. All these features make it possible to efficiently depress the dissolution of redox moieties in electrolytes and to boost the electrical conductivity of whole electrode. When employed as a cathode in LIBs, the two-dimensional porous nanosheets exhibit outstanding cycle stability of 395mAhg(-1) at 5Ag(-1) for more than 5100 cycles and excellent rate capability of 135mAhg(-1) at a high current density of 15Ag(-1).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据