期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 26, 页码 6791-6794出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201403823
关键词
alpha-arylation; C-O activation; nickel; oxidative addition; synthetic methods
资金
- JSPS [220GR049]
- MEXT [25105720, 25708005]
- JSPS
- World Premier International Research Center (WPI) Initiative (Japan)
- Grants-in-Aid for Scientific Research [25105720, 13J03280, 25708005] Funding Source: KAKEN
The nickel-catalyzed alpha-arylation of ketones with readily available phenol derivatives (esters and carbamates) provides access to useful alpha-arylketones. For this transformation, 3,4-bis(dicyclohexylphosphino)thiophene (dcypt) was identified as a new, enabling, air-stable ligand for this transformation. The intermediate of an assumed C-O oxidative addition was isolated and characterized by X-ray crystal-structure analysis.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据
分享论文
