期刊
APPLIED CATALYSIS A-GENERAL
卷 318, 期 -, 页码 17-21出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.apcata.2006.10.033
关键词
palladium; carbon; catalysts; hydrogenation; cyclododecatriene
Carbon-supported palladium catalysts were prepared by ion-exchange and precipitation/deposition methods on various activated carbons. Pd/carbon catalysts with Pd particles ranging from 1.5 to 10 nm were thus obtained. The liquid phase hydrogenation of c,t,t-1,5,9-cyclododecatriene was carried out on these catalysts. A structure-sensitivity was observed with a decrease of TOF on smallest Pd particles. The highest yield to half-hydrogenated cyclododecene was observed on large Pd particles (similar to 10 nm). (c) 2006 Elsevier B.V. All rights reserved.
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