期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 52, 期 18, 页码 4744-4788出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201204921
关键词
cooperative catalysis; NH effect; organometallic catalysis; self-assembly; supramolecular catalysis
资金
- NSFC [21121062, 21032007, 91127041]
- Major Basic Research Development Program of China [2010CB833300]
- Chinese Academy of Sciences
The organometallic approach is one of the most active topics in catalysis. The application of NH functionality in organometallic catalysis has become an important and attractive concept in catalyst design. NH moieties in the modifiers of organometallic catalysts have been shown to have various beneficial functions in catalysis by molecular recognition through hydrogen bonding to give catalystsubstrate, ligandligand, ligandcatalyst, and catalystcatalyst interactions. This Review summarizes recent progress in the development of the organometallic catalysts based on the concept of cooperative catalysis by focusing on the NH moiety.
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