期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 4, 页码 1048-1052出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307311
关键词
dendrimers; heterocycles; iridium; supramolecular chemistry; synthesis design
资金
- 973 Project [2009CB623601, 2009CB930603]
- National Natural Science Foundation of China [20923003, 21174144, 21074130]
- Science Fund for Creative Research Groups [20921061]
A blue-emitting iridium dendrimer, namely B-G2, has been successfully designed and synthesized with a second-generation oligocarbazole as the dendron, which is covalently attached to the emissive tris[2-(2,4-difluorophenyl)-pyridyl]iridium(III) core through a nonconjugated link to form an efficient self-host system in one dendrimer. Unlike small molecular phosphors and other phosphorescent dendrimers, B-G2 shows a continuous enhancement in the device efficiency with increasing doping concentration. When using neat B-G2 as the emitting layer, the nondoped device is achieved without loss in efficiency, thus giving a state-of-art EQE as high as 15.3% (31.3cdA(-1), 28.9lmW(-1)) along with CIE coordinates of (0.16, 0.29).
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