期刊
TETRAHEDRON LETTERS
卷 48, 期 9, 页码 1637-1639出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2006.12.136
关键词
palladium catalyzed; ring opening; 4-amino-1-butanols; hydrogenation; tetrahydrofuran hydroperoxide
资金
- NIGMS NIH HHS [R25 GM058042, S06 GM065299, S06 GM065299-01A10001] Funding Source: Medline
Reaction of primary aromatic amines with peroxidic tetrahydrofuran (THF) in the presence of hydrogen and 10%, palladium on carbon catalyst results in THF ring opening to give 4-N-arylamino-1-butanols in a good yield. The reaction mechanism is believed to involve a free-radical sequence resulting in an imino alcohol subsequently reduced to product. (c) 2007 Elsevier Ltd. All rights reserved.
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