期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 5, 页码 1355-1359出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201306527
关键词
acid treatment; double 4-ring; germanium; post-synthesis treatment; zeolites
资金
- NSFC of China [20925310, U1162102, 21373089]
- Ministry of Science and Technology [2012BAE05B02]
- Programs Foundation of Ministry of Education [2012007613000]
- Shanghai Leading Academic Discipline Project [B409]
- Shanghai Synchrotron Radiation Facility [j13sr0021]
Germanosilicates, an important family of zeolites with increasing number of members and attractive porosities, but containing a large quantity of unstable Ge atoms in the framework, meet with great obstacles in terms of limited thermal and hydrothermal stability when it comes to practical use. A facile stabilization method thus has been developed to substitute isomorphously Ge atoms for Si atoms, giving rise to ultrastable siliceous analogues of the pristine germanosilicates.
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