期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 2, 页码 526-529出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201306507
关键词
fluorine; radicals; structure elucidation; substituent effects; sulfur
资金
- National Science Foundation [CHE0957544]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [0957544, 1464936] Funding Source: National Science Foundation
Substituted alkenyl aryl tetrafluoro-(6)-sulfanes have been prepared by the direct addition of readily accessible chlorotetrafluorosulfanyl arenes to primary alkynes. Substitution of an apical fluorine of the pentafluorosulfanyl group enables modulation of the reactivity of this little explored functional group while at the same time facilitating the direct investigation of aryl substituent effects on the aryl tetrafluorosulfanyl-substituted products.
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