期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 4, 页码 1092-1097出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201308396
关键词
charge-transfer interactions; orthogonal hydrogen bonding; reverse micelles; reverse vesicles; thermal transitions
资金
- CSIR, New Delhi, India
- SERB, India [SR/S1/OC-18/2012]
A naphthalene diimide (NDI) building block containing hydrazide (H1) and hydroxy (H2) groups self-assembled into a reverse-vesicular structure in methylcyclohexane by orthogonal H-bonding and -stacking. At an elevated temperature (LCST=43 degrees C), destruction of the assembled structure owing to selective dissociation of H2-H2 Hbonding led to macroscopic precipitation. Further heating resulted in homogeneous redispersion of the sample at 70 degrees C (UCST) and the formation of a reverse-micellar structure. In the presence of a pyridine (H3)-functionalized pyrene (PY) donor, a supramolecular dyad (NDI-PY) was formed by H2-H3 H-bonding. Slow transformation into an alternate NDI-PY stack occurred by a folding process due to the charge-transfer interaction between NDI and PY. The mixed NDI-PY assembly exhibited a morphology transition from a reverse micelle (with a NDI-PY mixed-stack core) below the LCST to another reverse micelle (with a NDI core) above the UCST via a denatured intermediate.
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