期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 2, 页码 543-547出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201308701
关键词
aldehydes; asymmetric catalysis; benzylic ethers; CH functionalization; organocatalysis
资金
- National Science Foundation of China [21202093, 30925038]
- Young Scientist Foundation Grant of Shandong Province [BS2013YY001]
The first one-pot enantioselective oxidative coupling of cyclic benzylic ethers with aldehydes has been developed. A variety of benzylic ethers were transformed into the corresponding oxygen heterocycles with high enantioselectivity. Mechanistic experiments were conducted to determine the nature of the reaction intermediates. The application of this strategy to coupling reactions with other nucleophiles besides aldehydes was also explored.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据