期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 3, 页码 742-746出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307019
关键词
C-H activation; N-heterocyclic carbenes; palladium; sulfones; Suzuki-Miyaura coupling
资金
- JSPS
- Nagoya University
Triarylmethanes, which are valuable structures in materials, sensing and pharmaceuticals, have been synthesized starting from methyl phenyl sulfone as an inexpensive and readily available template. The three aryl groups were installed through two sequential palladium-catalyzed C-H arylation reactions, followed by an arylative desulfonation. This method provides a new synthetic approach to multisubstituted triarylmethanes using readily available haloarenes and aryl boronic acids, and is also valuable for the preparation of unexplored triarylmethane-based materials and pharmaceuticals.
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