期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 2, 页码 442-446出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201307976
关键词
bifunctional catalysts; carbon nanotubes; core-shell structures; lithium-air batteries; ruthenium
资金
- Japanese Funding Program for World-Leading Innovative R&D on Science and Technology (FIRST Program)
- Chinese Fund [2014CB932300]
A RuO2 shell was uniformly coated on the surface of core CNTs by a simple sol-gel method, and the resulting composite was used as a catalyst in a rechargeable Li-O-2 battery. This core-shell structure can effectively prevent direct contact between the CNT and the discharge product Li2O2, thus avoiding or reducing the formation of Li2CO3, which can induce large polarization and lead to charge failure. The battery showed a high round-trip efficiency (ca. 79%), with discharge and charge overpotentials of 0.21 and 0.51V, respectively, at a current of 100mAg(total)(-1). The battery also exhibited excellent rate and cycling performance.
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