期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 2, 页码 376-383出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201303761
关键词
carbene; lanthanides; methylidene; rare-earth metals
Transition-metal carbene complexes have been known for about 50years and widely applied as reagents and catalysts in organic transformations. In contrast, the carbene chemistry of the rare-earth metals is much less developed, but has attracted the research interest in the recent years. In this field rare-earth-metal alkylidene, especially methylidene, compounds are an emerging class of compounds with a high synthetic potential for organometallic chemistry and maybe in the future also for organic chemistry.
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