期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 3, 页码 706-710出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201305648
关键词
coordination polymers; luminescence; metal-organic frameworks; pulsed laser deposition; thin films
资金
- Deutsche Forschungsgemeinschaft
Highly luminescent switchable thin films of the dense framework (3)(infinity)[EuIm(2)] were deposited by a scanning laser ablation technique using a femtosecond laser. The films can be controlled in terms of film thickness and amount of material deposited such that the material properties of the bulk material are retained on the nanometer scale. Polycrystalline films are formed that can be switched between transparent at visible light and nontransparent at UV light due to the intrinsic luminescence of the hybrid material, expanding the concept of smart films. The new femtosecond pulsed laser deposition method also provides a novel approach for coatings with framework compounds and coordination polymers.
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