期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 53, 期 4, 页码 1160-1162出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201309073
关键词
carbohydrates; L-glucose; organic synthesis; rare sugars
资金
- Fundacion Ramon Areces
- Leverhulme Trust
The scarcity and expense of access to L-sugars and other rare sugars have prevented the exploitation of their biological potential; for example D-psicose, only recently available, has been recognized as an important new food. Here we give the definitive and cheap synthesis of 99.4% pure L-glucose from D-glucose which requires purification of neither intermediates nor final product other than extraction into and removal of solvents; a simple crystallization will raise the purity to >99.8%.
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