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卷 114, 期 1-2, 页码 36-40出版社
SPRINGER
DOI: 10.1007/s10562-007-9032-x
关键词
copper(II) catalyst; alginate; biopolymer; cycloaddition; alkynes; azides; oxidative coupling; phenols
Copper(II) ions immobilized onto a biopolymer (sodium alginate) is an effective heterogeneous catalyst for 1,3-dipolar cycloaddition of alkynes with azides and oxidative coupling of 2-naphthols and phenols in water to afford the 1,4-disubstituted 1,2,3-triazoles and biaryl compounds respectively in good yields. The catalyst was recovered quantitatively by simple filtration and reused for several times without significant loss of activity.
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