期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 51, 期 41, 页码 10236-10254出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.201203269
关键词
non-chelate-assisted C?H activation; reactivity; selectivity; simple arenes
资金
- European Research Council under the European Community/ERC [25936]
- Alfried Krupp von Bohlen and Halbach Foundation
- Fonds der Chemischen Industrie
The use of coordinating moieties as directing groups for the functionalization of aromatic C?H bonds has become an established tool to enhance reactivity and induce regioselectivity. Nevertheless, with regard to the synthetic applicability of C?H activation, there is a growing interest in transformations in which the directing group can be fully abandoned, thus allowing the direct functionalization of simple benzene derivatives. However, this approach requires the disclosure of new strategies to achieve reactivity and to control selectivity. In this review, recent advances in the emerging field of non-chelate-assisted C?H activation are discussed, highlighting some of the most intriguing and inspiring examples of induction of reactivity and selectivity.
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