4.7 Article

Diarylmethanols by catalyzed asymmetric aryl transfer reactions onto aldehydes using boronic acids as aryl source

期刊

ADVANCED SYNTHESIS & CATALYSIS
卷 349, 期 4-5, 页码 703-708

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600390

关键词

arylboronic acids; C-C bond formation; diarylmethanols; enantioselective catalysis; organozinc reagents

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Using a planar-chiral ferrocene as catalyst and combinations of functionalized aldchydes and substituted arylboronic acids as starting materials, asymmetric aryl transfer reactions give access to structurally diverse, optically active diarylinethanols in high yields and enantioselectivities.

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