Depletion and enrichment processes in the lithospheric mantle beneath the Kola Peninsula (Russia): Evidence from spinel lherzolite and wehrlite xenoliths

A suite of spinel lherzolite and wehrlite xenoliths from a Devonian kimberlite dyke near Kandalaksha, Kola Peninsula, Russia, has been studied to determine the nature of the lithospheric mantle beneath the northern Baltic Shield. Olivine modal estimates and Fo content in the spinet lherzolite xenoliths reveal that the lithosphere beneath the Archaean-Proterozoic crust has some similarities to Phanerozoic lithospheric mantle elsewhere. Modal metasomatism is indicated by the presence of Ti-rich and Ti-poor phlogopite, pargasite, apatite and picroilmenite in the xenoliths. Wehrlite xenoliths are considered to represent localised high-pressure cumulates from mafic-ultramafic melts trapped within the mantle as veins or tenses. Equilibration temperatures range from 775 to 969 degrees C for the spinet lherzolite xenoliths and from 817 to 904 degrees C for the wehrlites. Laser ablation ICP-MS data for incompatible trace elements in primary clinopyroxenes and metasomatic amphiboles from the spinet lherzolites show moderate levels of LREE enrichment. Replacement clinopyroxenes in the wehrlites are less enriched in LREE but richer in TiO2. Fractional melt modelling for Y and Yb concentrations in clinopyroxenes from the spinet lherzolites indicates 7-8% partial melting of a primitive source. Such a volume of partial melt could be related to the 2.4-2.5 Ga intrusion of basaltic magmas (now metamorphosed to garnet granulites) in the lower crust of the northern Baltic Shield. The lithosphere beneath the Kola Peninsula has undergone several episodes of metasomatism. Both the spinel lherzolites and wehrlites were subjected to an incomplete carbonatitic metasomatic event, probably related to an early carbonatitic phase associated with the 360-380 Ma Devonian alkaline magmatism. This resulted in crystallisation of secondary clinopyroxene rims at the expense of primary orthopyroxenes, with development of secondary forsteritic olivine and apatite. Two separate metasomatic events resulted in the crystallisation of the Ti-Fe-rich amphibole, phlogopite and ilmenite in the wehrlites and the low Ti-Fe amphibole and phlogopite in the spinet lherzolites. Alternatively, a single metasomatic event with a chemically evolving melt may have produced the significant compositional differences seen in the amphibole and phlogopite between the spinet lherzolites and wehrlites. The calculated REE pattern of a melt in equilibrium with clinopyroxenes from a cpx-rich pocket is identical to that of the kimberlite host, indicating a close petrological relationship. (C) 2006 Elsevier B.V. All rights reserved.