期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 72, 期 5, 页码 1811-1813出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo0624086
关键词
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Dirhodium(II) salts efficiently catalyze the three-component assembly reaction of an imine, diazoacetonitrile (DAN), and an activated alkynyl coupling partner to form substituted 1,2-diarylpyrroles in moderate to good yields. The transition-metal-catalyzed decomposition of the diazo compound in the presence of the imine presumably generates a transient azomethine ylide that undergoes cycloaddition with dipolarophiles in a highly convergent manner.
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