期刊
TETRAHEDRON
卷 63, 期 10, 页码 2142-2147出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2006.12.091
关键词
Amberlyst 15; glycosylation; trichloroacetimidate; oligosaccharide
Amberlyst 15 acidic resin has been shown to be a mild and effective activator for the glycosylation with commonly used disarmed glycosyl trichloroacetimidate donors. Glucosylation, galactosylation, rhamnosylation, and lactosylation of a panel of representative alcohol and thiol acceptors promoted by Amberlyst 15 allowed for the formation of structurally diverse O- or S-linked oligosaccharides and glycosylated amino acids in moderate to excellent yields. (c) 2007 Elsevier Ltd. All rights reserved.
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