In the presence of RuO2, Pb-deficient lead tungstates, PbxWO4 (x < 1.0), showed higher photocatalytic activity compared to stoichiometric PbWO4 for water decomposition. The highest activity was obtained at x = 0.75 in the range x = 0.2-1.1. The effects of the electronic structures on the photocatalysis are suggested.
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