期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 9, 页码 2442-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja068522n
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The luminescence from the neptunyl(VI) ion and its polyoxometallate complexes has been investigated in solution for the first time. Emission occurs in the near-IR and is quenched effectively by O-H oscillators in the hydrated ion. The polyoxometallate complexes exclude solvent from the neptunyl coordination sphere and have much more intense and longer-lived emission spectra.
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