Crystalline morphology of isotactic polypropylene (iPP) in injection molded poly(ethylene terephthalate) (PET)/iPP microfibrillar blends

The poly(ethylene terephthalate) (PET)/isotactic polypropylene (iPP) in situ microfibrillar blends have been prepared through a slit die extrusion-hot stretch-quenching process, in which PET assumes microfibrils with 0.5-15 mu m in diameter depending on the hot stretching ratios (HSR, the area of the transverse section of the die to the area of the transverse section of the extrudate). The injection molded specimens of virgin iPP and the PET/iPP blends were prepared by conventional injection molding (CIM) and by shear controlled orientation injection molding (SCORIM), respectively. The effect of shear stress and PET phase with different shape on superstructures and their distribution of injection molded microfibrillar samples were investigated by means of small angle X-ray scattering (SAXS) and wide angle X-ray scattering (WAXS). The shear (or elongational) flow during CIM and SCORIM can induce oriented lamellae (i.e. kebabs induced by shish). The shishkebab structure appears not only in the skin and intermediated layers of CIM samples, but also in the whole region of SCORIM samples. For the neat iPP samples, a more stretched shish-kebab structure with higher orientation degree can be obtained in the interior region (intermediate and core layers) by the SCORIM method; moreover, the SCORIM can result in the growth of beta-form crystal both in intermediate layer and in core layer, which only appears in intermediate layer of the neat iPP samples obtained by CIM. For the PET/iPP blends, interestingly, the addition of microfibrils as well as their aspect ratios can affect the orientation degree of kebabs only in the intermediate layers, and the addition of microfibrils with a low aspect ratio can bring out a considerable increase in the orientation degree of kebabs along the flow direction. However, for the SCORIM, the addition of microfibrils seems to be a minor effect on the orientation degree of kebabs, and it tends to hamper the formation of a more stretched shish-kebab structure and suppresses the growth of beta-form crystal distinctly. Furthermore, It appears from experiment that gamma-form crystals can grow successfully in this oriented iPP melt with the synergistic effect of shear and pressure only when the growth of beta crystals can be restrained by some factors, such as the PET dispersed phase and thermal conditions (cooling rate). (c) 2007 Elsevier Ltd. All rights reserved.