期刊
ORGANIC LETTERS
卷 9, 期 6, 页码 1037-1040出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol063072p
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资金
- NIGMS NIH HHS [GM 54909] Funding Source: Medline
Chiral quaternary carbon stereocenters can be established with high diastereoselectivity by a silylene transfer/Ireland-Claisen rearrangement. The utility of this method was demonstrated by application to a synthesis of (+)-5-epi-acetomycin.
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