Heterogeneous chemistry of the NO3 free radical and N2O5 on decane flame soot at ambient temperature:: Reaction products and kinetics

The interaction of NO3 free radical and N2O5 with laboratory flame soot was investigated in a Knudsen flow reactor at T = 298 K equipped with beam-sampling mass spectrometry and in situ REMPI detection of NO2 and NO. Decane (C10H22) has been used as a fuel in a co-flow device for the generation of gray and black soot from a rich and a lean diffusion flame, respectively. The gas-phase reaction products of NO3 reacting with gray soot were NO, N2O5, HONO, and HNO3 with HONO being absent on black soot. The major loss of NO3 is adsorption on gray and black soot at yields of 65 and 59%, respectively, and the main gas-phase reaction product is N2O5 owing to heterogeneous recombination of NO3 with NO2 and NO according to NO3 + {C} -> NO + products. HONO was quantitatively accounted for by the interaction of NO2 with gray soot in agreement with previous work. Product N2O5 was generated through heterogeneous recombination of NO3 with excess NO2, and the small quantity of HNO3 was explained by heterogeneous hydrolysis of N2O5. The reaction products of N2O5 on both types of soot were equimolar amounts of NO and NO2, which suggest the reaction N2O5 + {C} -> N2O3(ads) + products with N2O3(ads) decomposing into NO + NO2. The initial and steady-state uptake coefficients gamma(0) and gamma(ss) of both NO3 and N2O5 based on the geometric surface area continuously increase with decreasing concentration at a concentration threshold for both types of soot. gamma(ss) of NO3 extrapolated to [NO3] -> 0 is independent of the type of soot and is 0.33 +/- 0.06 whereas gamma(ss) for [N2O5] -> 0 is (2.7 +/- 1.0) x 10(-2) and (5.2 +/- 0.2) x 10(-2) for gray and black soot, respectively. Above the concentration threshold of both NO3 and N2O5, gamma(ss) is independent of concentration with gamma(ss)(NO3) = 5.0 x 10(-2) and gamma(ss)(N2O5) = 5.0 x 10(-3). The inverse concentration dependence of gamma below the concentration threshold reveals a complex reaction mechanism for both NO3 and N2O5. The atmospheric significance of these results is briefly discussed.