期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 11, 页码 3062-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja066834k
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Defect-site enriched nanocrystalline ceria prepared by an alcoholysis method favors oxidative dehydrogenation of ethylbenzene using nitrous oxide with high conversion and selectivity at much lower temperatures compared to ceria samples prepared by other conventional methods. A direct correlation exists between the concentration of -Ce4+-O--Ce3+-type defect sites and the reaction rates and, hence, the activation temperature required for the reaction.
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