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Reverse-keggin ions: Polycondensation of antimonate ligands give inorganic cryptand

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 11, 页码 3042-+

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AMER CHEMICAL SOC
DOI: 10.1021/ja068214p

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Reverse-Keggin ions are reported in which a p-block element (antimony) occupies the twelve vertices of a truncated tetrahedron while a d-block element (manganese or zinc) occupies the tetrahedral central cavity. The exterior of the reverse-Keggins also acts as tridentate ligands to further d-block centers.

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