The mechanism responsible for C-H activation in Ir(acac)(2)(OCH3)(C6H6) has been identified and described as an internal electrophilic substitution (IES) mechanism, on the basis of orbital changes and predicted reactivity. In this IES mechanism, the lone pair on a M-X ligand forms an X-H bond, while the orbital making up the M-X bond turns into a coordinating lone pair.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据