期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 129, 期 12, 页码 3510-+出版社
AMER CHEMICAL SOC
DOI: 10.1021/ja0701614
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资金
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0910014] Funding Source: National Science Foundation
The use of preformed sodium carboxylates as substrates led to the first observation of facile Pd-insertions into sp(3) beta-C-H bonds in simple aliphatic acids. Consequently, Pd-catalyzed methylation and arylation of o-C-H bonds in benzoic acids and beta-C-H bonds in aliphatic acids using either a phenylboronate, methylboronic acid, or ArI have been achieved via a C-H activation/C-C coupling sequence.
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