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Concise synthesis of the bacterial DNA primase inhibitor (+)-Sch 642305

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卷 9, 期 7, 页码 1327-1329

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AMER CHEMICAL SOC
DOI: 10.1021/ol070173u

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A highly convergent, enantioselective synthesis of (+)-Sch 642305 is presented, which features a Mukaiyama-Michael addition followed by allylation to establish the syn-anti relationship of the three contiguous stereocenters. The 10-membered macrolactone was formed through ring-closing metathesis.

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