期刊
ORGANIC LETTERS
卷 9, 期 7, 页码 1323-1326出版社
AMER CHEMICAL SOC
DOI: 10.1021/ol070159h
关键词
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资金
- NIGMS NIH HHS [1 R15 GM075960-01, R15 GM075960, R15 GM075960-01] Funding Source: Medline
The oxidation of selected anions (N-3(-), SCN-, I-, and Br-) by ceric ammonium nitrate (CAN) in the presence of substituted cyclopropyl alcohols provides a novel approach to beta-functionalized ketones. The protocol has a number of advantages including short reaction times, ease of reagent handling, and mild, neutral reaction conditions. Overall, this method provides an alternative pathway to important starting materials and intermediates in organic synthesis.
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