期刊
JOURNAL OF POLYMER RESEARCH
卷 14, 期 2, 页码 99-105出版社
SPRINGER
DOI: 10.1007/s10965-006-9086-2
关键词
photoinitiated; cationic polymerizations; p-trimethoxytrityl salts
Photoinitiated cationic polymerizations of cyclohexene oxide, tetrahydrofuran and N-vinylcarbazole were investigated in dichloromethane at 25 degrees C, using stable, soluble and nonhygroscopic p-trimethoxytrityl salts having nonnucleophilic anions such as SbF6-, AsF6-, PF6-, BF4-, and SbCl6-. The effects of anion, polymerization time, concentration of the salt and the intensity of light on the polymerization reaction are presented.
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