期刊
CHEMICAL ENGINEERING SCIENCE
卷 62, 期 8, 页码 2139-2153出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2006.12.069
关键词
chemical reactors; fluidization; circulating fluidized bed; particulate processes; powder technology; residence time distribution
Gas/solid and catalytic gas phase reactions in CFBs use different operating conditions, with a strict control of the solids residence time and limited back-mixing only essential in the latter applications. Since conversion proceeds with residence time, this residence time is an essential parameter in reactor modelling. To determine the residence time and its distribution (RTD), previous studies used either stimulus response or single tracer particle studies. The experiments of the present research were conducted at ambient conditions and combine both stimulus response and particle tracking measurements. Position emission particle tracking (PEPT) continuously tracks individual radioactive tracer particles, thus yielding data on particle movement in real time, defining particle velocities and population density plots. Pulse tracer injection measurements of the RTD were performed in a 0.1 in I.D. riser. PEPT experiments were performed in a small (similar to 0.05 m I.D.) riser, using F-18-labelled sand and radish seed. The operating conditions varied from 1 to 10 m/s as superficial velocity, and 25-622 kg/m(2)s as solids circulation rate. Experimental results were compared with fittings from several models. Although the model evaluation shows that the residence time distribution (RTD) of the experiments shifts from near plug flow to perfect mixing (when the solids circulation rate decreases), none of the models fits the experimental results over the broad (U, G)-range. The particle slip velocity was found to be considerably below the theoretical value in core/annulus flow (due to cluster formation), but to be equal at high values of the solids circulation rate and superficial gas velocity. The transition from mixed to plug flow was further examined. At velocities near U-tr the CFB-regime is either not fully developed and/or mixing occurs even at high solids circulation rates. This indicates the necessity of working at U > approx. (U-tr + 1) m/s to have a stable solids circulation, irrespective of the need to operate in either mixed or plug flow mode. At velocities above this limit, plug flow is achieved when the solids circulation rate G > approx. 200kg/m(2) s. Solids back-mixing occurs at lower G and the operating mode can be described by the core/annulus approach. The relative sizes of core and annulus, as well as the downward particle velocity in the annulus (similar to U-t) are defined from PEPT measurements. Own and literature data were finally combined in a core/annulus vs. plug flow diagram. These limits of working conditions were developed from experiments at ambient conditions. Since commercial CFB reactors normally operate at a higher temperature and/or pressure, gas properties such as density and viscosity will. be different and possibly influence the gas-solid flow and mixing. Further tests at higher temperatures and pressures are needed or scaling laws must be considered. At ambient conditions, reactors requiring pure plug flow must operate at U > approx. (U-tr + 1) m/s and G > approx. 200 kg/m(2)s. If back-mixing is required, as in gas/solid reactors, operation at U > approx. (U-tr + 1) m/s and G < approx. 150 kg/m(2)s is recommended. (c) 2007 Elsevier Ltd. All rights reserved.
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