期刊
SOLID STATE NUCLEAR MAGNETIC RESONANCE
卷 31, 期 2, 页码 63-71出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.ssnmr.2007.01.002
关键词
solid-state nuclear magnetic resonance; paramagnetic effect; meteorite organic matter; magnetic particles; H-1 sidebands
Organic matter from the Murchison meteorite shows pronounced spinning sidebands of the H-1 MAS NMR spectrum and exhibits a large bulk magnetization of 0.75 emu/g extrapolated to 94 kOe at 300K. By comparison with data of diamagnetic polystyrene and laponite clay mixed with ferrimagnetic gamma-Fe2O3 nano-particles, we show that the spinning sidebands arise from a combination of dipolar couplings of a given H-1 to magnetic particles, seen in a backscattered-electron image, and to other protons. Signal loss and significant broadening of protonated-carbon peaks in C-13 MAS NMR spectra of polystyrene with Fe2O3 nano-particles is demonstrated, and implications for C-13 NMR spectroscopy of Murchison meteorite are discussed. (C) 2007 Elsevier Inc. All rights reserved.
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